As important and valuable alternatives to transition-metal-catalysis, free-radical strategies for C–Si bond construction via selective C–H/Si–H functionalization have been developed recently. These new reactions along with their suggested mechanisms are summarized and discussed here.
X. Shang and Z. Liu, Org. Biomol. Chem., 2016, 14, 7829 DOI: 10.1039/C6OB00797J
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