Issue 23, 2016
From the journal:

Organic & Biomolecular Chemistry

Iridium- and rhodium-catalyzed C–H activation and formyl arylation of benzaldehydes under chelation-assistance†

Xifa Yang,a   He Wang,a   Xukai Zhoua  and  Xingwei Li*a  

* Corresponding authors

a Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian 116023, China
E-mail: xwli@dicp.ac.cn

Abstract

Mild and efficient synthesis of benzophenones via Ir(III)- and Rh(III)-catalyzed, directing group-assisted formyl C–H arylation of benzaldehydes has been achieved using diaryliodonium salts, in which Rh(III) and Ir(III) catalysts exhibited a complementary substrate scope.

Graphical abstract: Iridium- and rhodium-catalyzed C–H activation and formyl arylation of benzaldehydes under chelation-assistance

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Article information

DOI
https://doi.org/10.1039/C6OB00825A
Article type
Communication
Submitted
18 Apr 2016
Accepted
14 May 2016
First published
17 May 2016

Org. Biomol. Chem., 2016,14, 5233-5237

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Iridium- and rhodium-catalyzed C–H activation and formyl arylation of benzaldehydes under chelation-assistance

X. Yang, H. Wang, X. Zhou and X. Li, Org. Biomol. Chem., 2016, 14, 5233 DOI: 10.1039/C6OB00825A

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