Herein, the themes of coordination-driven self-assembly, host–guest interaction, and supramolecular polymerization are unified in an orthogonal fashion to deliver main-chain supramolecular polycatenanes.
![Graphical abstract: Supramolecular main-chain polycatenanes formed by orthogonal metal ion coordination and pillar[5]arene-based host–guest interaction](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C6PY01617K&imageInfo.ImageIdentifier.Year=2016)
H. Xing and B. Shi, Polym. Chem., 2016, 7, 6159 DOI: 10.1039/C6PY01617K
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