Synthesis and photophysical properties of multi-Ru2+ terpyridine complexes: from di-nuclear linear to star-shaped hexa-nuclear architectures

Jie Yuan; Zhilong Jiang; Die Liu; Yiming Li; Pingshan Wang

doi:10.1039/C5QI00181A

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Synthesis and photophysical properties of multi-Ru²⁺ terpyridine complexes: from di-nuclear linear to star-shaped hexa-nuclear architectures†

Jie Yuan,‡^a Zhilong Jiang,‡^a Die Liu,^a Yiming Li^a and Pingshan Wang*^a

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* Corresponding authors

^a College of Chemistry and Chemical Engineering, Central South University, Changsha-410083, Hunan, China
E-mail: chemwps@csu.edu.cn
Fax: +0086-731-88830651

Abstract

A series of terpyridine based Ru²⁺ complexes G1, G2, G3, and G4 were designed and synthesized, the solubility of complexes was enhanced by introducing a multiple tailed long aliphatic chain; full characterization has been performed with ¹H NMR, ¹³C NMR, ESI-MS and UV-vis measurements. Electrochemical behaviours of these complexes have been investigated.

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Article information

DOI: https://doi.org/10.1039/C5QI00181A
Article type: Research Article
Submitted: 19 Sep 2015
Accepted: 01 Dec 2015
First published: 02 Dec 2015

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Inorg. Chem. Front., 2016,3, 268-273

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Synthesis and photophysical properties of multi-Ru²⁺ terpyridine complexes: from di-nuclear linear to star-shaped hexa-nuclear architectures

J. Yuan, Z. Jiang, D. Liu, Y. Li and P. Wang, Inorg. Chem. Front., 2016, 3, 268 DOI: 10.1039/C5QI00181A

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