Issue 26, 2016
From the journal:

RSC Advances

Synthesis and structure of new polyhedral Ni, Na- and Cu, Na-metallasiloxanes with tolyl substituent at the silicon atom†

Anton A. Anisimov,a   Yuriy N. Kononevich,a   Pavel V. Zhemchugov,a   Sergey A. Milenin,b   Alexander A. Korlyukov,ac   Ul'yana S. Tsareva,a   Alexander S. Peregudov,a   Pavel V. Dorovatovskii,d   Yuliya A. Molodtsova,a   Rina U. Takazova,a   Olga I. Shchegolikhina*a  and  Aziz M. Muzafarovab  

* Corresponding authors

a A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991 Moscow, Russian Federation
E-mail: olga@ineos.ac.ru

b N.S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 117393 Moscow, Russian Federation

c Pirogov Russian National Research Medical University, 117997 Moscow, Russian Federation

d National Research Centre “Kurchatov Institute”, 123182 Moscow, Russian Federation

Abstract

Two new polyhedral tolyl-containing metallasiloxanes, {(Na+)2[TolSi(O)O−]6(Ni2+)4(Na+)4(OH−)2[TolSi(O)O−]6}*(EtOH)14(H2O)2 and {[CuSi(O)O−]12(Cu2+)4(Na+)4}*(EtOH)8}, and two new large stereoregular cyclosiloxanes, cis-[TolSi(O)OSiMe3]6 and tris-cis-tris-trans-[TolSi(O)OSiMe3]12, have been synthesized and their structures have been determined by X-ray crystallography.

Graphical abstract: Synthesis and structure of new polyhedral Ni, Na- and Cu, Na-metallasiloxanes with tolyl substituent at the silicon atom

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5RA26414F
Article type
Paper
Submitted
10 Dec 2015
Accepted
17 Feb 2016
First published
23 Feb 2016

RSC Adv., 2016,6, 22052-22060

Permissions

Request permissions

Synthesis and structure of new polyhedral Ni, Na- and Cu, Na-metallasiloxanes with tolyl substituent at the silicon atom

A. A. Anisimov, Y. N. Kononevich, P. V. Zhemchugov, S. A. Milenin, A. A. Korlyukov, U. S. Tsareva, A. S. Peregudov, P. V. Dorovatovskii, Y. A. Molodtsova, R. U. Takazova, O. I. Shchegolikhina and A. M. Muzafarov, RSC Adv., 2016, 6, 22052 DOI: 10.1039/C5RA26414F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements