Issue 33, 2016
From the journal:

RSC Advances

Azacalix[2]arene[2]carbazoles: synthesis, structure and properties†

Hui Xu,a   Fang-Jun Qian,a   Qiao-Xia Wu,a   Min Xue,b   Yong Yang*a  and  Yong-Xiang Chen*c  

* Corresponding authors

a School of Science, Department of Chemistry, Zhejiang Sci-Tech University, Hangzhou 310018, China
E-mail: yangyong@zstu.edu.cn

b School of Science, Department of Physics, Zhejiang Sci-Tech University, Hangzhou 310018, China

c Department of Chemistry, Tsinghua University, Beijing, China
E-mail: chen-yx@mail.tsinghua.edu.cn

Abstract

A new type of –NH– bridged azacalix[2]arene[2]carbazoles has been synthesized by aromatic nucleophilic substitution reaction via one pot and/or fragment coupling strategy. Both symmetric and unsymmetric macrocycles are obtained. X-ray single crystal analysis reveals 1,3-alternation conformation of the macrocycle. The spectroscopic and electrochemical properties of the macrocycles are also explored.

Graphical abstract: Azacalix[2]arene[2]carbazoles: synthesis, structure and properties

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Article information

DOI
https://doi.org/10.1039/C6RA01197G
Article type
Communication
Submitted
14 Jan 2016
Accepted
07 Mar 2016
First published
11 Mar 2016

RSC Adv., 2016,6, 27988-27992

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Azacalix[2]arene[2]carbazoles: synthesis, structure and properties

H. Xu, F. Qian, Q. Wu, M. Xue, Y. Yang and Y. Chen, RSC Adv., 2016, 6, 27988 DOI: 10.1039/C6RA01197G

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