Tuning the composition of rare earth sesquioxides Gd2−xLaxO3:Eu3+ to control phase transitions at a high temperature to design new highly sensitive luminescence-based thermal sensors

Abstract

The C-form (SG: Ia) → B-form (SG: C2/m) phase transition of RE₂O₃ rare earth sesquioxides is described for the first time for face centred cubic–hexagonal close-packed array transformations. Based on XRD data analysis, the temperature of the C → B phase transition in Gd_2−xLa_xO₃ compositions (0 < x < 0.5) was controlled by adjusting the Gd/La atomic ratio and varies between 1100 °C and 1400 °C. Taking into account the various environments of rare earth oxides in C and B allotropic forms, Eu³⁺ was used as a local probe to obtain photoluminescence spectra (emission and excitation spectra, luminescence decay time curves). The spectra significantly changed during the phase transition, which occurred within a small temperature range. Furthermore, coupling Rietveld XRD data analysis for the long-range order signature with optical emission spectroscopy to probe the local environment provides a clear view of the C → B phase transition, allowing for the design of new highly sensitive thermal sensors at high temperatures.