Issue 92, 2016, Issue in Progress

Temperature-induced single-crystal-to-single-crystal transformation of a binuclear Mn(ii) complex into a 1D chain polymer

Abstract

Dehydration of complex [Mn2(4-Apha)4(H2O)2]·2H2O (1, 4-AphaH = 4-aminophenylhydroxamic acid) upon heating at 393 K led to the removal of coordinated water molecules to give anhydrous [Mn(4-Apha)2] (2). The crystal structure transformation has been characterized by variable temperature PXRD and TGA-DSC analysis. Single crystal X-ray diffraction analysis reveals that complex 1 exhibits a binuclear structure and complex 2 shows a 1D chain structure. Both of them show antiferromagnetic exchange interactions between the metal centers.

Graphical abstract: Temperature-induced single-crystal-to-single-crystal transformation of a binuclear Mn(ii) complex into a 1D chain polymer

Supplementary files

Article information

Article type
Paper
Submitted
02 Jun 2016
Accepted
12 Sep 2016
First published
13 Sep 2016

RSC Adv., 2016,6, 89192-89197

Temperature-induced single-crystal-to-single-crystal transformation of a binuclear Mn(II) complex into a 1D chain polymer

P. Jiang, F. Peng and Y. Chen, RSC Adv., 2016, 6, 89192 DOI: 10.1039/C6RA14364D

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