Issue 6, 2016
From the journal:

Reaction Chemistry & Engineering

A greener process for flow C–H chlorination of cyclic alkanes using in situ generation and on-site consumption of chlorine gas†

Takahide Fukuyama,*a   Masashi Tokizane,a   Akihiro Matsuia  and  Ilhyong Ryu*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan
E-mail: fukuyama@c.s.osakafu-u.ac.jp, ryu@c.s.osakafu-u.ac.jp

Abstract

Photo-chlorination of C–H bonds was investigated by using a photo microreactor and gaseous chlorine in situ generated from HCl and NaOCl. Under photoirradiation using a black light (15 W, 352 nm), chlorination of hydrocarbons proceeded smoothly within 1 min residence time to give chlorinated products in good yields.

Graphical abstract: A greener process for flow C–H chlorination of cyclic alkanes using in situ generation and on-site consumption of chlorine gas

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Article information

DOI
https://doi.org/10.1039/C6RE00159A
Article type
Communication
Submitted
06 Sep 2016
Accepted
28 Sep 2016
First published
10 Oct 2016

React. Chem. Eng., 2016,1, 613-615

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A greener process for flow C–H chlorination of cyclic alkanes using in situ generation and on-site consumption of chlorine gas

T. Fukuyama, M. Tokizane, A. Matsui and I. Ryu, React. Chem. Eng., 2016, 1, 613 DOI: 10.1039/C6RE00159A

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