A redox active switch for lanthanide luminescence in phenolate complexes†
Abstract
The reversible oxidation of coordinated phenolates into phenoxyl radicals results in a dramatic quenching (>95%) of the luminescence of the f metal ion.
* Corresponding authors
a
Département de Chimie Moléculaire, Chimie Inorganique Redox (CIRE), UMR CNRS 5250, Université Grenoble-Alpes, B. P. 53, 38041 Grenoble Cedex 9, France
E-mail:
fabrice.thomas@univ-grenoble-alpes.fr
b Laboratoire de Reconnaissance Ionique et Chimie de Coordination SCIB, UMR-E3 CEA-UJF, INAC, CEA-Grenoble, 17 rue des Martyrs, 38054 Grenoble Cedex 09, France
The reversible oxidation of coordinated phenolates into phenoxyl radicals results in a dramatic quenching (>95%) of the luminescence of the f metal ion.
J. K. Molloy, O. Jarjayes, C. Philouze, L. Fedele, D. Imbert and F. Thomas, Chem. Commun., 2017, 53, 605 DOI: 10.1039/C6CC07942C
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