2D 7Li Ultrafast CT-COSY: a new tool for the rapid measurement of tiny homonuclear lithium scalar couplings

G. Hamdoun; B. Gouilleux; M. Sebban; G. Barozzino-Consiglio; A. Harrison-Marchand; P. Giraudeau; J. Maddaluno; H. Oulyadi

doi:10.1039/C6CC08744B

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2D ⁷Li Ultrafast CT-COSY: a new tool for the rapid measurement of tiny homonuclear lithium scalar couplings†

G. Hamdoun,^a B. Gouilleux,^b M. Sebban,^a G. Barozzino-Consiglio,^a A. Harrison-Marchand,^a P. Giraudeau,^bc J. Maddaluno^a and H. Oulyadi*^a

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* Corresponding authors

^a Normandie Univ, UNIROUEN, INSA Rouen, CNRS, COBRA (UMR 6014 & FR 3038), 76000 Rouen, France

^b CEISAM, Université de Nantes, UMR CNRS 6230, 2 rue de la Houssinière, 44322 Nantes, France

^c Institut Universitaire de France, 1 rue Descartes, Paris, France

Abstract

The measurement of small homonuclear ²J_{⁷Li–⁷Li} scalar couplings relying on constant time (CT) COSY NMR suffers from strong time limitations. We describe the first Ultrafast CT COSY experiment on lithium 7, which provides a considerable acceleration in the study of the aggregation state and dynamics of n-BuLi/MeLi complexes.

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Article information

DOI: https://doi.org/10.1039/C6CC08744B
Article type: Communication
Submitted: 31 Oct 2016
Accepted: 28 Nov 2016
First published: 28 Nov 2016

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Chem. Commun., 2017,53, 220-223

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2D ⁷Li Ultrafast CT-COSY: a new tool for the rapid measurement of tiny homonuclear lithium scalar couplings

G. Hamdoun, B. Gouilleux, M. Sebban, G. Barozzino-Consiglio, A. Harrison-Marchand, P. Giraudeau, J. Maddaluno and H. Oulyadi, Chem. Commun., 2017, 53, 220 DOI: 10.1039/C6CC08744B

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