Issue 5, 2017
From the journal:

Chemical Communications

A platinum(ii)–palladium(ii)–nickel(ii) heterotrimetallic coordination polymer showing a cooperative effect on catalytic hydrogen evolution†

Naoto Kuwamura,a   Yoshinari Kuriokaa  and  Takumi Konno ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan
E-mail: konno@chem.sci.osaka-u.ac.jp

Abstract

Stepwise construction of a 1D heterotrimetallic coordination polymer containing all three group 10 metal ions via an ammineplatinum(II) metalloligand with D-penicillamine is reported. This system showed a significant enhancement in heterogeneous catalytic activity for electrochemical hydrogen evolution by the stepwise introduction of PdII and NiII into the PtII metalloligand.

Graphical abstract: A platinum(ii)–palladium(ii)–nickel(ii) heterotrimetallic coordination polymer showing a cooperative effect on catalytic hydrogen evolution

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Article information

DOI
https://doi.org/10.1039/C6CC08789B
Article type
Communication
Submitted
02 Nov 2016
Accepted
29 Nov 2016
First published
05 Dec 2016
This article is Open Access
Creative Commons BY license

Chem. Commun., 2017,53, 846-849

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A platinum(II)–palladium(II)–nickel(II) heterotrimetallic coordination polymer showing a cooperative effect on catalytic hydrogen evolution

N. Kuwamura, Y. Kurioka and T. Konno, Chem. Commun., 2017, 53, 846 DOI: 10.1039/C6CC08789B

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