Issue 1, 2017
From the journal:

Chemical Communications

Convenient route to tetraarylphosphonium polyelectrolytes via metal-catalysed P–C coupling polymerisation of aryl dihalides and diphenylphosphine†

Wang Wan,a   Xiaoyan Yanga  and  Rhett C. Smith*ab  

* Corresponding authors

a Department of Chemistry, Clemson University, Clemson, SC 29634, USA

b Centre for Optical Materials Science and Engineering Technologies, Clemson University, Anderson, SC 29634, USA

Abstract

A P–C bond-forming reaction has been applied to the convenient preparation of tetraarylphosphonium polyelectrolytes (TPELs) from aryl dihalides and diphenylphosphine. A TPEL having a thermal decomposition temperature of 460 °C that is also stable to heating at 65 °C in 6 M NaOH(aq) for at least 24 h has been prepared by this method.

Graphical abstract: Convenient route to tetraarylphosphonium polyelectrolytes via metal-catalysed P–C coupling polymerisation of aryl dihalides and diphenylphosphine

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Article information

DOI
https://doi.org/10.1039/C6CC08938K
Article type
Communication
Submitted
08 Nov 2016
Accepted
21 Nov 2016
First published
08 Dec 2016

Chem. Commun., 2017,53, 252-254

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Convenient route to tetraarylphosphonium polyelectrolytes via metal-catalysed P–C coupling polymerisation of aryl dihalides and diphenylphosphine

W. Wan, X. Yang and R. C. Smith, Chem. Commun., 2017, 53, 252 DOI: 10.1039/C6CC08938K

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