The first sumanene derivatives functionalized at the convex face of the internal carbon were reported. The structure of racemic hydroxysumanenone was confirmed by X-ray crystal analysis. The obtained structure was composed of the single enantiomer.
N. Ngamsomprasert, J. Dang, S. Higashibayashi, Y. Yakiyama and H. Sakurai, Chem. Commun., 2017, 53, 697 DOI: 10.1039/C6CC08970D
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