Construction of 2D covalent organic frameworks by taking advantage of the variable orientation of imine bonds

Shun-Qi Xu; Rong-Ran Liang; Tian-Guang Zhan; Qiao-Yan Qi; Xin Zhao

doi:10.1039/C6CC09906H

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Construction of 2D covalent organic frameworks by taking advantage of the variable orientation of imine bonds†

Shun-Qi Xu,‡^a Rong-Ran Liang,

‡^a Tian-Guang Zhan,^a Qiao-Yan Qi^a and Xin Zhao

*^a

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* Corresponding authors

^a CAS Key Laboratory of Synthetic and Self-assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China
E-mail: xzhao@sioc.ac.cn

Abstract

A model system has been established to construct two-dimensional (2D) covalent organic frameworks (COFs) by taking advantage of the variable orientation of imine bonds. During the assembly process, the imine bonds adopt an unprecedented heterodromous orientation to facilitate the formation of the COFs.

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Article information

DOI: https://doi.org/10.1039/C6CC09906H
Article type: Communication
Submitted: 13 Dec 2016
Accepted: 30 Jan 2017
First published: 30 Jan 2017
This article is Open Access

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Chem. Commun., 2017,53, 2431-2434

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Construction of 2D covalent organic frameworks by taking advantage of the variable orientation of imine bonds

S. Xu, R. Liang, T. Zhan, Q. Qi and X. Zhao, Chem. Commun., 2017, 53, 2431 DOI: 10.1039/C6CC09906H

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Chemical Communications

Construction of 2D covalent organic frameworks by taking advantage of the variable orientation of imine bonds†

Abstract

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Construction of 2D covalent organic frameworks by taking advantage of the variable orientation of imine bonds

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