The aromatic core in dipyridyl linker ligands is found to impact the mode of 2-fold interpenetration in hybrid ultramicroporous materials formed by pillared square grid networks. An analysis of the crystal structures suggests that linker conformation and weak interactions between the linkers in adjacent networks might explain this phenomenon.
A. Bajpai, M. Lusi and M. J. Zaworotko, Chem. Commun., 2017, 53, 3978 DOI: 10.1039/C6CC10217D
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