A novel and expedient one-pot synthesis of thiazino[2,3,4-hi]indole derivatives from o-haloaryl enamines and o-bromothiophenols has been developed. The tandem oxidative coupling/heteroannulation reactions exhibit high selectivity and good efficiency. The polycyclic heterocyclic products obtained might be useful in medicinal chemistry and materials science.
![Graphical abstract: One-pot synthesis of thiazino[2,3,4-hi]indole derivatives through a tandem oxidative coupling/heteroannulation process](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C7CC00992E&imageInfo.ImageIdentifier.Year=2017)
X. Mao, T. Tong, S. Fan, L. Fang, J. Wu, X. Wang, H. Kang and X. Lv, Chem. Commun., 2017, 53, 4718 DOI: 10.1039/C7CC00992E
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