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The structures and properties of two mononuclear Dy(III) enantiomeric pairs were dramatically controlled by crystallization temperature; the enantiomeric pair with coordinated chiral N,N′-donor ligands exhibits enhanced single-ion magnetic, ferroelectric and chiroptical properties with respect to the other one with protonated chiral N,N′-donor ligands.

Graphical abstract: Enhanced single-ion magnetic and ferroelectric properties of mononuclear Dy(iii) enantiomeric pairs through the coordination role of chiral ligands

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