A highly porous metal–organic framework for large organic molecule capture and chromatographic separation

Pei-Zhou Li; Jie Su; Jie Liang; Jia Liu; Yuanyuan Zhang; Hongzhong Chen; Yanli Zhao

doi:10.1039/C7CC01063J

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A highly porous metal–organic framework for large organic molecule capture and chromatographic separation†

Pei-Zhou Li,‡^a Jie Su,‡^b Jie Liang,‡^a Jia Liu,^a Yuanyuan Zhang,^a Hongzhong Chen^a and Yanli Zhao

*^ac

Author affiliations

* Corresponding authors

^a Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore
E-mail: zhaoyanli@ntu.edu.sg

^b Berzelii Centre EXSELENT on Porous Materials and Inorganic and Structural Chemistry, Department of Materials and Environmental Chemistry, Stockholm University, 106 91 Stockholm, Sweden

^c School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore

Abstract

A highly porous metal–organic framework (MOF) with large pores was successfully obtained via solvothermal assembly of a “click”-extended tricarboxylate ligand and Zn(II) ions. The inherent feature of large-molecule accessible pores endows the MOF with a unique property for utilization toward large guest molecules.

This article is part of the themed collection: Most downloaded articles of 2017: Inorganic and Materials Chemistry

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Article information

DOI: https://doi.org/10.1039/C7CC01063J
Article type: Communication
Submitted: 10 Feb 2017
Accepted: 03 Mar 2017
First published: 03 Mar 2017

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Chem. Commun., 2017,53, 3434-3437

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A highly porous metal–organic framework for large organic molecule capture and chromatographic separation

P. Li, J. Su, J. Liang, J. Liu, Y. Zhang, H. Chen and Y. Zhao, Chem. Commun., 2017, 53, 3434 DOI: 10.1039/C7CC01063J

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Chemical Communications

A highly porous metal–organic framework for large organic molecule capture and chromatographic separation†

Abstract

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A highly porous metal–organic framework for large organic molecule capture and chromatographic separation

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