Supported Pd nanoclusters with enhanced hydrogen spillover for NOx removal via H2-SCR: the elimination of “volcano-type” behaviour

Zhezhe Peng; Zongyuan Li; Yun-Quan Liu; Shuai Yan; Jianing Tong; Duo Wang; Yueyuan Ye; Shuirong Li

doi:10.1039/C7CC02235B

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Supported Pd nanoclusters with enhanced hydrogen spillover for NO_x removal via H₂-SCR: the elimination of “volcano-type” behaviour†

Zhezhe Peng,^a Zongyuan Li,^a Yun-Quan Liu,*^a Shuai Yan,^a Jianing Tong,^a Duo Wang,^a Yueyuan Ye^a and Shuirong Li

*^a

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* Corresponding authors

^a College of Energy, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Xiamen University, Xiamen 361102, China
E-mail: yq_liu@xmu.edu.cn, sli@xmu.edu.cn

Abstract

A rational design of a Pd catalyst with highly dispersed Pd nanoclusters on an Al doped ceria-based oxide for low temperature selective catalytic reduction of NO_x by hydrogen with excess O₂ was achieved. The supported Pd nanocluster shows a high hydrogen spillover ability and a NO_x conversion of >84% within 100–300 °C.

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Article information

DOI: https://doi.org/10.1039/C7CC02235B
Article type: Communication
Submitted: 24 Mar 2017
Accepted: 21 Apr 2017
First published: 21 Apr 2017

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Chem. Commun., 2017,53, 5958-5961

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Supported Pd nanoclusters with enhanced hydrogen spillover for NO_x removal via H₂-SCR: the elimination of “volcano-type” behaviour

Z. Peng, Z. Li, Y. Liu, S. Yan, J. Tong, D. Wang, Y. Ye and S. Li, Chem. Commun., 2017, 53, 5958 DOI: 10.1039/C7CC02235B

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