Issue 49, 2017

Concise synthesis of oxacyclic compounds using highly discriminative two-way transformations of α,β-unsaturated esters in the presence of enones

Abstract

Highly discriminative transformation of α,β-unsaturated esters in the presence of enones using two types of phosphonium salts, and their application to the synthesis of oxacyclic compounds in six steps in one pot have been achieved.

Graphical abstract: Concise synthesis of oxacyclic compounds using highly discriminative two-way transformations of α,β-unsaturated esters in the presence of enones

Supplementary files

Article information

Article type
Communication
Submitted
27 Apr 2017
Accepted
30 May 2017
First published
05 Jun 2017

Chem. Commun., 2017,53, 6605-6608

Concise synthesis of oxacyclic compounds using highly discriminative two-way transformations of α,β-unsaturated esters in the presence of enones

K. Morita, R. Ohta, H. Aoyama, K. Yahata, M. Arisawa and H. Fujioka, Chem. Commun., 2017, 53, 6605 DOI: 10.1039/C7CC03287K

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