Issue 64, 2017

Visible-light-induced thiotrifluoromethylation of terminal alkenes with sodium triflinate and benzenesulfonothioates

Abstract

An unconventional reductive quenching cycle was developed to realize the visible-light-induced thiotrifluoromethylation of terminal alkenes. CF3SO2Na was used as an easy to handle CF3 radical source to afford the desired products in moderate to good yields. Mild reaction conditions and a broad substrate scope feature in this transformation.

Graphical abstract: Visible-light-induced thiotrifluoromethylation of terminal alkenes with sodium triflinate and benzenesulfonothioates

Supplementary files

Article information

Article type
Communication
Submitted
06 May 2017
Accepted
06 Jul 2017
First published
07 Jul 2017

Chem. Commun., 2017,53, 8968-8971

Visible-light-induced thiotrifluoromethylation of terminal alkenes with sodium triflinate and benzenesulfonothioates

W. Kong, H. An and Q. Song, Chem. Commun., 2017, 53, 8968 DOI: 10.1039/C7CC03520A

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