NHC-stabilized 1-hydrosilaimine: synthesis, structure and reactivity

Debabrata Dhara; Thangavel Vijayakanth; Milan Kr. Barman; Khevath Praveen Kumar Naik; Nicolas Chrysochos; Cem B. Yildiz; Ramamoorthy Boomishankar; Carola Schulzke; Vadapalli Chandrasekhar; Anukul Jana

doi:10.1039/C7CC03912C

NHC-stabilized 1-hydrosilaimine: synthesis, structure and reactivity†

Debabrata Dhara,^a Thangavel Vijayakanth,^b Milan Kr. Barman,^a Khevath Praveen Kumar Naik,^a Nicolas Chrysochos,^c Cem B. Yildiz,

*^d Ramamoorthy Boomishankar,

*^b Carola Schulzke,

*^c Vadapalli Chandrasekhar

*^ef and Anukul Jana

*^a

Author affiliations

* Corresponding authors

^a Tata Institute of Fundamental Research Centre for Interdisciplinary Sciences 21, Brundavan Colony, Narsingi, Hyderabad-500075, India
E-mail: ajana@tifrh.res.in

^b Department of Chemistry, Indian Institute of Science Education and Research (IISER), Pune, Dr. Homi Bhabha Road, Pune 411008, India
E-mail: boomi@iiserpune.ac.in

^c Institut für Biochemie, Ernst-Moritz-Arndt Universität Greifswald Felix-Hausdorff-Straße 4, D-17487 Greifswald, Germany
E-mail: carola.schulzke@uni-greifswald.de

^d Department of Medicinal and Aromatic Plants, University of Aksaray, Aksaray, Turkey
E-mail: cemburakyildiz@aksaray.edu.tr

^e National Institute of Science Education and Research, Bhimpur-Padanpur, Jatni, Khurda, Bhubaneswar-752050, Odisha, India

^f Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016, India
E-mail: vc@iitk.ac.in

Abstract

A facile, straightforward synthesis of N-heterocyclic carbene (NHC)-stabilized 1-hydrosilaimine starting from a silicon(IV)-precursor is reported. It has been employed for the addition of an O–H bond of water under ambient conditions without any additional catalyst.

Chemical Communications

NHC-stabilized 1-hydrosilaimine: synthesis, structure and reactivity†

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NHC-stabilized 1-hydrosilaimine: synthesis, structure and reactivity

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