Nanoscale chemical imaging of the additive effects on the interfaces of high-voltage LiCoO2 composite electrodes

Abstract

X-ray photoemission electron microscopy (X-PEEM) of cycled LiCoO₂ composite electrodes has revealed the interfaces of various components within the composite electrodes and their dependence on additives in the electrolyte and the interplay of multiple components in the electrodes. This study visualizes CoF₂ distribution and Co–O bonding variation along with local component agglomeration and degradation. The obtained new insights will assist further development of long-life high-voltage LiCoO₂/C batteries.