Rapid and specific luminescence sensing of Cu(ii) ions with a porphyrinic metal–organic framework†
Abstract
We herein present a porphyrinic metal–organic framework (MOF) as a highly sensitive fluorescent probe targeting Cu(II) ions with a fast response. The well-isolated nature of porphyrin moieties within the framework greatly enable accessible recognition sites, which leads to an outstanding detection limit performance of 67 nM among MOF-based materials.