Issue 54, 2017
From the journal:

Chemical Communications

An NHC–phosphinidenyl as a synthon for new group 13/15 compounds†

Otfried Lemp,a   Markus Balmer,a   Kevin Reiter,b   Florian Weigendb  and  Carsten von Hänisch ORCID logo *a  

* Corresponding authors

a Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften (WZMW), Philipps Universität Marburg, Hans-Meerwein-Straße 4, 35032 Marburg, Germany
E-mail: haenisch@chemie.uni-Marburg.de

b Institut für Nanotechnologie, KIT, Campus Nord, Postfach 3640, 76021 Karlsruhe, Germany

Abstract

The parent phosphinidene SIMesPH (1) (SIMes = 1,3-bis(2,4,6-trimethylphenyl)imidazolin-2-ylidene) was treated with benzyl potassium to form the metalated species SIMesPK (2), which was used as a synthon for the new group 13/15 cycles and cage compounds [SIMesPGatBu2]2 (3), [SIMesP(GatBu2)2Cl] (4) and [K(SIMesP)3AltBu] (5).

Graphical abstract: An NHC–phosphinidenyl as a synthon for new group 13/15 compounds

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Article information

DOI
https://doi.org/10.1039/C7CC04422D
Article type
Communication
Submitted
15 May 2017
Accepted
09 Jun 2017
First published
22 Jun 2017

Chem. Commun., 2017,53, 7620-7623

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An NHC–phosphinidenyl as a synthon for new group 13/15 compounds

O. Lemp, M. Balmer, K. Reiter, F. Weigend and C. von Hänisch, Chem. Commun., 2017, 53, 7620 DOI: 10.1039/C7CC04422D

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