A highly stable polyoxometalate-based metal–organic framework with an ABW zeolite-like structure†
Abstract
A novel polyoxometalate-based metal–organic framework (POMOF) with an ABW network, NENU-601, was synthesized in situ. To the best of our knowledge, this is the first POMOF with a zeolite-like structure, which was designed by regulating the length and angle of mixed ligands and rationally choosing suitable Polyoxometalates (POMs) as nodes.