Issue 75, 2017
From the journal:

Chemical Communications

Ru atom-modified covalent triazine framework as a robust electrocatalyst for selective alcohol oxidation in aqueous electrolytes†

Shingi Yamaguchi,a   Kazuhide Kamiya, ORCID logo *bcd   Kazuhito Hashimoto ORCID logo e  and  Shuji Nakanishi*bc  

* Corresponding authors

a Department of Applied Chemistry, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

b Research Center for Solar Energy Chemistry, Osaka University, 1–3 Machikaneyama, Toyonaka, Osaka 560–8531, Japan
E-mail: kamiya@chem.es.osaka-u.ac.jp, nakanishi@chem.es.osaka-u.ac.jp

c Department of Chemistry, Graduate School of Engineering Science, Osaka University, 1–3 Machikaneyama, Toyonaka, Osaka 560–8531, Japan

d Japan Science and Technology Agency (JST) PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan

e National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan

Abstract

This work demonstrates that a single Ru atom-modified covalent triazine framework (Ru-CTF) has selectivity for the electrooxidation of benzyl alcohol in water over the oxygen evolution reaction. Additionally, Ru-CTF displayed higher stability than an immobilized Ru-organometallic complex due to the covalently cross-linked structure of CTF.

Graphical abstract: Ru atom-modified covalent triazine framework as a robust electrocatalyst for selective alcohol oxidation in aqueous electrolytes

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Article information

DOI
https://doi.org/10.1039/C7CC05841A
Article type
Communication
Submitted
27 Jul 2017
Accepted
04 Sep 2017
First published
04 Sep 2017

Chem. Commun., 2017,53, 10437-10440

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Ru atom-modified covalent triazine framework as a robust electrocatalyst for selective alcohol oxidation in aqueous electrolytes

S. Yamaguchi, K. Kamiya, K. Hashimoto and S. Nakanishi, Chem. Commun., 2017, 53, 10437 DOI: 10.1039/C7CC05841A

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