Issue 83, 2017
From the journal:

Chemical Communications

Chemically reprogrammable metal organic frameworks (MOFs) based on Diels–Alder chemistry†

Sana Nayab,ab   Vanessa Trouillet,c   Hartmut Gliemann,d   Silvana Hurrle,e   Peter G. Weidler,d   Saadia Rashid Tariq,b   Anja S. Goldmann, ORCID logo *ef   Christopher Barner-Kowollik ORCID logo *ef  and  Basit Yameen*a  

* Corresponding authors

a Department of Chemistry & Chemical Engineering, SBA School of Science and Engineering Lahore University of Management Sciences (LUMS), Lahore, Punjab 54792, Pakistan
E-mail: basit.yameen@lums.edu.pk

b Department of Chemistry, Lahore College for Women University, Jail Road, Lahore, Punjab 54000, Pakistan

c Institute for Applied Materials (IAM), Karlsruhe Institute of Technology (KIT) and Karlsruhe Nano Micro Facility (KNMF), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

d Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

e Macromolecular Architectures, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, 76131 Karlsruhe, Germany
E-mail: anja.goldmann@kit.edu, christopher.barner-kowollik@kit.edu

f School of Chemistry, Physics and Mechanical Engineering, Queensland University of Technology (QUT), 2 George Street, Brisbane, Australia
E-mail: a.goldmann@qut.edu.au, christopher.barnerkowollik@qut.edu.au

Abstract

We present the reversible Diels–Alder functionalization of metal organic frameworks (MOFs). Cyclopentadiene (Cp) functional MOFs are ligated with dienophiles to fabricate functional MOFs with a reprogrammable chemical nature. Our strategy thus constitutes an unprecedented concept for chemically dynamic MOFs able to be recoded.

Graphical abstract: Chemically reprogrammable metal organic frameworks (MOFs) based on Diels–Alder chemistry

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Article information

DOI
https://doi.org/10.1039/C7CC06150A
Article type
Communication
Submitted
07 Aug 2017
Accepted
26 Sep 2017
First published
05 Oct 2017

Chem. Commun., 2017,53, 11461-11464

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Chemically reprogrammable metal organic frameworks (MOFs) based on Diels–Alder chemistry

S. Nayab, V. Trouillet, H. Gliemann, S. Hurrle, P. G. Weidler, S. Rashid Tariq, A. S. Goldmann, C. Barner-Kowollik and B. Yameen, Chem. Commun., 2017, 53, 11461 DOI: 10.1039/C7CC06150A

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