Strategic design of a ruthenium catalyst for both CO2 reduction and H2O oxidation: the electronic influence of the co-ligands

Biswanath Das; Lida Ezzedinloo; Mohan Bhadbhade; Martin P. Bucknall; Stephen B. Colbran

doi:10.1039/C7CC06294J

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Strategic design of a ruthenium catalyst for both CO₂ reduction and H₂O oxidation: the electronic influence of the co-ligands†

Biswanath Das,^a Lida Ezzedinloo,^a Mohan Bhadbhade,^b Martin P. Bucknall^b and Stephen B. Colbran*^a

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* Corresponding authors

^a School of Chemistry, The University of New South Wales, Sydney, NSW 2052, Australia
E-mail: s.colbran@unsw.edu.au

^b Mark Wainwright Analytical Centre, The University of New South Wales, Sydney, NSW 2052, Australia

Abstract

A new ruthenium(II) complex capable of catalysing both CO₂ reduction and water oxidation was designed and synthesised. The electro-catalytic efficiency and robustness of the complex together with the electronic effect of its co-ligands were investigated to develop next generation dual activity electrocatalysts.

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Article information

DOI: https://doi.org/10.1039/C7CC06294J
Article type: Communication
Submitted: 11 Aug 2017
Accepted: 17 Aug 2017
First published: 17 Aug 2017

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Chem. Commun., 2017,53, 10006-10009

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Strategic design of a ruthenium catalyst for both CO₂ reduction and H₂O oxidation: the electronic influence of the co-ligands

B. Das, L. Ezzedinloo, M. Bhadbhade, M. P. Bucknall and S. B. Colbran, Chem. Commun., 2017, 53, 10006 DOI: 10.1039/C7CC06294J

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