Issue 91, 2017
From the journal:

Chemical Communications

Chiral binary metal–organic frameworks for asymmetric sequential reactions†

Zijian Li,a   Yan Liu,*a   Qingchun Xiaa  and  Yong Cui ORCID logo *a  

* Corresponding authors

a School of Chemistry and Chemical Engineering and State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China
E-mail: liuy@sjtu.edu.cn, yongcui@sjtu.edu.cn
Fax: +86 21-5474-1297

Abstract

Two chiral porous MOFs with precise and appropriate spatial arrangements of different metallosalen active sites are synthesized and used as efficient heterogeneous catalysts for asymmetric sequential alkene epoxidation/epoxide ring-opening reactions with enantioselectivity of up to 99%.

Graphical abstract: Chiral binary metal–organic frameworks for asymmetric sequential reactions

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Article information

DOI
https://doi.org/10.1039/C7CC06979K
Article type
Communication
Submitted
06 Sep 2017
Accepted
24 Oct 2017
First published
24 Oct 2017

Chem. Commun., 2017,53, 12313-12316

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Chiral binary metal–organic frameworks for asymmetric sequential reactions

Z. Li, Y. Liu, Q. Xia and Y. Cui, Chem. Commun., 2017, 53, 12313 DOI: 10.1039/C7CC06979K

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