Only a few studies on the use of halogen bonding in catalysis have been published so far. Herein, (benz)imidazolium-based halogen bond donors are used as catalysts in a Michael addition reaction. The most potent catalyst, a rigid atropisomer featuring two iodobenzimidazolium moieties, provided a rate acceleration versus a reference compound of ca. 50.
J. Gliese, S. H. Jungbauer and S. M. Huber, Chem. Commun., 2017, 53, 12052 DOI: 10.1039/C7CC07175B
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