Self-assembled [2]catenane in trapezoidal metallacycles with [Cp*Ir]-corners

Naifang Liu; Sheng-Li Huang; Xiaogang Liu; He-Kuan Luo; T. S. Andy Hor

doi:10.1039/C7CC08009C

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Self-assembled [2]catenane in trapezoidal metallacycles with [Cp*Ir]-corners†

Naifang Liu,^ab Sheng-Li Huang,

*^a Xiaogang Liu,^ab He-Kuan Luo

*^a and T. S. Andy Hor*^abc

Author affiliations

* Corresponding authors

^a Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 2 Fusionopolis Way, Innovis, #08-03, Singapore 138634, Singapore
E-mail: huangsl@imre.a-star.edu.sg, luoh@imre.a-star.edu.sg

^b Department of Chemistry, Faculty of Science, National University of Singapore, 3 Science, Drive 3, Singapore, Singapore

^c Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong
E-mail: andyhor@hku.hk

Abstract

A series of trapezoidal metallacycles were synthesized by the selective combination of a rigid with a flexible arm. [2]Catenane 3 was obtained by self-assembly when the cavity size of the trapezoidal rings was optimised.

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Article information

DOI: https://doi.org/10.1039/C7CC08009C
Article type: Communication
Submitted: 23 Oct 2017
Accepted: 07 Nov 2017
First published: 07 Nov 2017

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Chem. Commun., 2017,53, 12802-12805

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Self-assembled [2]catenane in trapezoidal metallacycles with [Cp*Ir]-corners

N. Liu, S. Huang, X. Liu, H. Luo and T. S. A. Hor, Chem. Commun., 2017, 53, 12802 DOI: 10.1039/C7CC08009C

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Chemical Communications

Self-assembled [2]catenane in trapezoidal metallacycles with [Cp*Ir]-corners†

Abstract

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Self-assembled [2]catenane in trapezoidal metallacycles with [Cp*Ir]-corners

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