Issue 11, 2017
From the journal:

CrystEngComm

Valence engineering of ionic molecular crystals: monovalent–divalent phase diagram for biferrocene–tetracyanoquinodimethane salts†

Tomoyuki Mochida, ORCID logo *a   Yusuke Funasako,ab   Takahiro Akasaka,a   Mikio Uruichic  and  Hatsumi Morid  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kobe University, Rokkodai, Nada, Hyogo 657-8501, Japan
E-mail: tmochida@platinum.kobe-u.ac.jp
Fax: +81 78 803 5679
Tel: +81 78 803 5679

b Department of Applied Chemistry, Faculty of Engineering, Tokyo University of Science, Yamaguchi, Sanyo-Onoda, Yamaguchi 756-0884, Japan

c Institute for Molecular Science, Myodaiji, Okazaki, Aichi 444-8585, Japan

d Institute for Solid State Physics, The University of Tokyo, Kashiwanoha, Kashiwa, Chiba 277-8581, Japan

Abstract

The valence state of ionic molecular solids composed of biferrocene derivatives (D) and tetracyanoquinodimethane (TCNQ) derivatives (A), either monovalent ([D]+[A2]−) or divalent ([D]2+[A2]2−), can be controlled by changing the redox potentials and molecular volumes of the components.

Graphical abstract: Valence engineering of ionic molecular crystals: monovalent–divalent phase diagram for biferrocene–tetracyanoquinodimethane salts

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Article information

DOI
https://doi.org/10.1039/C7CE00134G
Article type
Communication
Submitted
18 Jan 2017
Accepted
15 Feb 2017
First published
15 Feb 2017

CrystEngComm, 2017,19, 1449-1453

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Valence engineering of ionic molecular crystals: monovalent–divalent phase diagram for biferrocene–tetracyanoquinodimethane salts

T. Mochida, Y. Funasako, T. Akasaka, M. Uruichi and H. Mori, CrystEngComm, 2017, 19, 1449 DOI: 10.1039/C7CE00134G

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