Issue 6, 2017
From the journal:

Dalton Transactions

Molecular magnesium hydrides supported by an anionic triazacyclononane-type ligand†

S. Schnitzler,a   P. Cui,a   T. P. Spaniola  and  J. Okuda ORCID logo *a  

* Corresponding authors

a Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen, Germany
E-mail: jun.okuda@ac.rwth-aachen.de

Abstract

Molecular magnesium hydride with a terminal metal–hydrogen bond [Mg(iPr2TACN·AliBu3)H]2 supported by a monoanionic TACN-type ligand (TACN = 1,4-di-isopropyl-1,4,7-triazacyclononane) rearranges to form the dinuclear magnesium hydride [Mg(iPr2TACN·AlHiBu2)(μ-H)]2, exhibiting a rare Mg⋯H–Al interaction.

Graphical abstract: Molecular magnesium hydrides supported by an anionic triazacyclononane-type ligand

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Article information

DOI
https://doi.org/10.1039/C6DT04654A
Article type
Communication
Submitted
09 Dec 2016
Accepted
11 Jan 2017
First published
11 Jan 2017

Dalton Trans., 2017,46, 1761-1765

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Molecular magnesium hydrides supported by an anionic triazacyclononane-type ligand

S. Schnitzler, P. Cui, T. P. Spaniol and J. Okuda, Dalton Trans., 2017, 46, 1761 DOI: 10.1039/C6DT04654A

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