Issue 11, 2017
From the journal:

Dalton Transactions

Highly efficient cold-white light emission in a [Au2CuCl2(P∩N)2]PF6 type salt†

Elnaz Hobbollahi,a   Manuela List,b   Benjamin Hupp,c   Fabian Mohr,d   Raphael J. F. Berger,*e   Andreas Steffen*c  and  Uwe Monkowius ORCID logo *a  

* Corresponding authors

a Institute of Inorganic Chemistry, Johannes Kepler University Linz, Altenbergerstr. 69, A-4040 Linz, Austria
E-mail: uwe.monkowius@jku.at

b Institut für Chemische Technologie Organischer Stoffe, Johannes Kepler University Linz, Altenbergerstr. 69, A-4040 Linz, Austria

c Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany
E-mail: andreas.steffen@uni-wuerzburg.de

d Fakultät für Mathematik und Naturwissenschaften, Anorganische Chemie, Bergische Universität Wuppertal, 42119 Wuppertal, Germany

e Chemie und Physik der Materialien, Abteilung Materialchemie, Paris-Lodron Universität Salzburg, Hellbrunner Str. 34, 5020 Salzburg, Austria
E-mail: Raphael.Berger@sbg.ac.at

Abstract

In the trinuclear, heterometallic cluster compound [Au2CuCl2(P∩N)2]PF6 metallophilic interactions give rise to very efficient cold-white light emission as a result of at least two thermally non-equilibrated emissive triplet states (one of mainly Cu → py and the other of Au → py character, respectively) with exceptional spin–orbit coupling and short emission lifetimes, which are competitive to PtII- and IrIII-based emitters.

Graphical abstract: Highly efficient cold-white light emission in a [Au2CuCl2(P∩N)2]PF6 type salt

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Article information

DOI
https://doi.org/10.1039/C7DT00180K
Article type
Communication
Submitted
16 Jan 2017
Accepted
09 Feb 2017
First published
09 Feb 2017
This article is Open Access
Creative Commons BY license

Dalton Trans., 2017,46, 3438-3442

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Highly efficient cold-white light emission in a [Au2CuCl2(P∩N)2]PF6 type salt

E. Hobbollahi, M. List, B. Hupp, F. Mohr, R. J. F. Berger, A. Steffen and U. Monkowius, Dalton Trans., 2017, 46, 3438 DOI: 10.1039/C7DT00180K

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