Issue 30, 2017

Lantern-shaped 3d–4f high-nuclearity clusters with magnetocaloric effect

Abstract

Two lantern-shaped, high-nuclearity 3d–4f clusters {Ln52Ni52}(Ln = Gd and Dy) were synthesized by using iminodiacetic acid (H2IDA) and isonicotinic acid (HIN) as the co-ligand under solvothermal conditions. Magnetic studies show a large magnetocaloric effect (MCE) for the gadolinium analogue.

Graphical abstract: Lantern-shaped 3d–4f high-nuclearity clusters with magnetocaloric effect

Supplementary files

Article information

Article type
Communication
Submitted
31 May 2017
Accepted
27 Jun 2017
First published
27 Jun 2017

Dalton Trans., 2017,46, 9745-9749

Lantern-shaped 3d–4f high-nuclearity clusters with magnetocaloric effect

Q. Lin, J. Li, Y. Dong, G. Zhou, Y. Song and Y. Xu, Dalton Trans., 2017, 46, 9745 DOI: 10.1039/C7DT01978E

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