Issue 30, 2017

UV-induced single-crystal-to-single-crystal conversion from a coordination ladder to a two-dimensional network through an intermolecular carbon–carbon coupling reaction

Abstract

UV irradiation of a ladder-like coordination polymer induces a stereospecific [2 + 2] photocycloaddition reaction of each pair of adjacent olefinic ligands from neighboring coordination ladders and thus affords a unique two-dimensional coordination network in a single-crystal-to-single-crystal manner. The conversion exhibits photocontrolled fluorescence.

Graphical abstract: UV-induced single-crystal-to-single-crystal conversion from a coordination ladder to a two-dimensional network through an intermolecular carbon–carbon coupling reaction

Supplementary files

Article information

Article type
Communication
Submitted
01 Jun 2017
Accepted
30 Jun 2017
First published
30 Jun 2017

Dalton Trans., 2017,46, 9755-9759

UV-induced single-crystal-to-single-crystal conversion from a coordination ladder to a two-dimensional network through an intermolecular carbon–carbon coupling reaction

J. Chen, Y. Hou, Q. Zhou, H. Zhang and D. Liu, Dalton Trans., 2017, 46, 9755 DOI: 10.1039/C7DT01989K

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