Covalent self-assembly of the specific RSSR isomer of 14-membered tetrakisphosphine

T. I. Wittmann; E. I. Musina; D. B. Krivolapov; I. A. Litvinov; S. A. Kondrashova; Sh. K. Latypov; A. A. Karasik; O. G. Sinyashin

doi:10.1039/C7DT03010J

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Covalent self-assembly of the specific RSSR isomer of 14-membered tetrakisphosphine†

T. I. Wittmann,^a E. I. Musina,

*^a D. B. Krivolapov,^a I. A. Litvinov,^a S. A. Kondrashova,^a Sh. K. Latypov,

^a A. A. Karasik^a and O. G. Sinyashin^a

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* Corresponding authors

^a A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Russia
E-mail: elli@iopc.ru

Abstract

The first representative of the specific RSSR isomer of 14-membered tetrakisphosphine has been obtained instead of the RRRR/SSSS isomer predicted according to the empirical rule formulated recently. The geometry of the obtained 14-P₄N₂ is preorganized for the dicopper complex formation with the unique coordination mode in the row of P₄N₂ corands.

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DOI: https://doi.org/10.1039/C7DT03010J
Article type: Communication
Submitted: 13 Jul 2017
Accepted: 21 Aug 2017
First published: 01 Sep 2017
This article is Open Access

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Dalton Trans., 2017,46, 12417-12420

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Covalent self-assembly of the specific RSSR isomer of 14-membered tetrakisphosphine

T. I. Wittmann, E. I. Musina, D. B. Krivolapov, I. A. Litvinov, S. A. Kondrashova, Sh. K. Latypov, A. A. Karasik and O. G. Sinyashin, Dalton Trans., 2017, 46, 12417 DOI: 10.1039/C7DT03010J

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Dalton Transactions

Covalent self-assembly of the specific RSSR isomer of 14-membered tetrakisphosphine†

Abstract

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Covalent self-assembly of the specific RSSR isomer of 14-membered tetrakisphosphine

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