Issue 48, 2017

O2 activation at a trispyrazolylborato nickel(ii) malonato complex

Abstract

To support mechanistic inferences made for an iron-based dioxygenase model, a nickel analogue, i.e. a TpNi-malonate (1) was prepared. 1 proved to represent a rare case of a nickel complex reacting with O2 in a controlled manner – mechanistically different from the iron case – and leads to hydroxylation of the malonate.

Graphical abstract: O2 activation at a trispyrazolylborato nickel(ii) malonato complex

Supplementary files

Article information

Article type
Communication
Submitted
27 Oct 2017
Accepted
19 Nov 2017
First published
27 Nov 2017

Dalton Trans., 2017,46, 16792-16795

O2 activation at a trispyrazolylborato nickel(II) malonato complex

S. Hoof, M. Sallmann, C. Herwig, B. Braun-Cula and C. Limberg, Dalton Trans., 2017, 46, 16792 DOI: 10.1039/C7DT04056C

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