Issue 1, 2017
From the journal:

Green Chemistry

Copper-catalyzed S-methylation of sulfonyl hydrazides with TBHP for the synthesis of methyl sulfones in water†

Yu Yang,‡a   Yajie Bao,‡a   Qianqian Guan,a   Qi Sun,a   Zhenggen Zhaa  and  Zhiyong Wang*a  

* Corresponding authors

a Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Soft Matter Chemistry and Department of Chemistry & Collaborative Innovation Center of Suzhou Nano Science and Technology, University of Science and Technology of China, Hefei, P. R. China
E-mail: zwang3@ustc.edu.cn
Fax: (+86) 551-360-3185

Abstract

A copper-catalyzed S-methylation of sulfonyl hydrazides with TBHP was efficiently developed, providing a variety of methyl sulfones with good to excellent yields. The reaction can be carried out in water smoothly without any ligand or additive under mild conditions and this catalyst-in-water can be recycled several times.

Graphical abstract: Copper-catalyzed S-methylation of sulfonyl hydrazides with TBHP for the synthesis of methyl sulfones in water

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Article information

DOI
https://doi.org/10.1039/C6GC03142K
Article type
Communication
Submitted
15 Nov 2016
Accepted
28 Nov 2016
First published
28 Nov 2016

Green Chem., 2017,19, 112-116

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Copper-catalyzed S-methylation of sulfonyl hydrazides with TBHP for the synthesis of methyl sulfones in water

Y. Yang, Y. Bao, Q. Guan, Q. Sun, Z. Zha and Z. Wang, Green Chem., 2017, 19, 112 DOI: 10.1039/C6GC03142K

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