Enantiospecific total syntheses of spiromeroterpenoid natural products (−)-F1839-I and (−)-corallidictyals B and D were achieved using the environmentally benign and highly atom economical Lewis acid catalysed Friedel–Crafts reaction and a highly regio- and stereoselective spirocyclic C–O bond formation reaction.
D. H. Dethe, B. D. Dherange, S. Ali and M. M. Parsutkar, Org. Biomol. Chem., 2017, 15, 65 DOI: 10.1039/C6OB02322C
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