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Abstract | Cited by

The first example of transition metal-free enantioselective 1,2-silylation of aromatic aldehydes is reported. This protocol enables an easy access to chiral α-hydroxysilanes from readily available aromatic aldehydes.

Graphical abstract: Metal-free enantioselective addition of nucleophilic silicon to aromatic aldehydes catalyzed by a [2.2]paracyclophane-based N-heterocyclic carbene catalyst

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