Ruthenium-catalyzed regioselective allylic amination of 2,3,3-trifluoroallylic carbonates†
Abstract
We demonstrated the ruthenium-catalyzed allylic amination of 2,3,3-trifluoroallylic carbonates with several types of amines. The reactions proceeded with several types of amines, and succeeded in obtaining polyfluorinated terminal alkenes possessing branched allylic amines as a single regioisomer.