Issue 25, 2017
From the journal:

Organic & Biomolecular Chemistry

A flexible 1,2-cis α-glycosylation strategy based on in situ adduct transformation†

Jhe-Cyuan Hu,a   Ai-Fen Wendy Feng,a   Bo-Yao Chang,a   Chun-Hung Lin*b  and  Kwok-Kong Tony Mong ORCID logo *a  

* Corresponding authors

a Applied Chemistry Department, National Chiao Tung University of Taiwan, 1001, University Road, Hsinchu, Taiwan, Republic of China
E-mail: tmong@mail.ncut.edu.tw
Fax: +886-3-5723764

b Institute of Biological Chemistry, Academia Sinica, Room 802, 128, Academia Road Sec. 2, Nankang, Taipei 115, Taiwan, Republic of China

Abstract

A flexible 1,2-cis α-selective glycosylation strategy for a wide range of glycosyl donors and acceptors has been developed, which is based on an in situ adduct transformation protocol. Based on this strategy, both NFM-derived and iodide covalent adducts can be accessed for glycosylation. Using low temperature NMR spectroscopy, the aforementioned glycosyl adducts were detected.

Graphical abstract: A flexible 1,2-cis α-glycosylation strategy based on in situ adduct transformation

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Article information

DOI
https://doi.org/10.1039/C7OB00839B
Article type
Paper
Submitted
04 Apr 2017
Accepted
31 May 2017
First published
01 Jun 2017

Org. Biomol. Chem., 2017,15, 5345-5356

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A flexible 1,2-cis α-glycosylation strategy based on in situ adduct transformation

J. Hu, A. W. Feng, B. Chang, C. Lin and K. T. Mong, Org. Biomol. Chem., 2017, 15, 5345 DOI: 10.1039/C7OB00839B

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