Acyclic nucleoside phosphonates have been prepared in a straightforward manner and in high yields by an enantioselective palladium-catalyzed allylic substitution involving nucleic bases as nucleophiles followed by cross-metathesis reaction with diethyl allylphosphonate.
M. Azzouz, S. Soriano, M. Escudero-Casao, M. I. Matheu, S. Castillón and Y. Díaz, Org. Biomol. Chem., 2017, 15, 7227 DOI: 10.1039/C7OB01478C
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