Issue 4, 2017

Silver-catalyzed phosphonylation of unprotected propargylic alcohols for the synthesis of allenylphosphoryl compounds

Abstract

A facile and efficient method of silver-catalyzed phosphonylation of unprotected propargylic alcohols with P(O)H compounds has been established, in which a wide variety of allenylphosphine oxides were obtained in moderate to excellent yields. This transformation could be conducted under mild reaction conditions without a ligand, base, and additive.

Graphical abstract: Silver-catalyzed phosphonylation of unprotected propargylic alcohols for the synthesis of allenylphosphoryl compounds

Supplementary files

Article information

Article type
Research Article
Submitted
30 Nov 2016
Accepted
20 Jan 2017
First published
24 Jan 2017

Org. Chem. Front., 2017,4, 608-611

Silver-catalyzed phosphonylation of unprotected propargylic alcohols for the synthesis of allenylphosphoryl compounds

L. Mao, Y. Li and S. Yang, Org. Chem. Front., 2017, 4, 608 DOI: 10.1039/C6QO00767H

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