Issue 19, 2017, Issue in Progress

Carboxylation of styrenes with CBr4 and DMSO via cooperative photoredox and cobalt catalysis

Abstract

Cooperative photoredox and cobalt catalyzed carboxylation of styrenes with CBr4 to afford the corresponding α,β-unsaturated carboxylic acids has been realized through radical addition and Kornblum (DMSO) oxidation. DMSO serves as the oxidant, oxygen source and solvent under these photocatalytic conditions.

Graphical abstract: Carboxylation of styrenes with CBr4 and DMSO via cooperative photoredox and cobalt catalysis

Supplementary files

Article information

Article type
Paper
Submitted
27 Dec 2016
Accepted
07 Feb 2017
First published
13 Feb 2017
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2017,7, 11233-11243

Carboxylation of styrenes with CBr4 and DMSO via cooperative photoredox and cobalt catalysis

C. Song, P. Chen and Y. Tang, RSC Adv., 2017, 7, 11233 DOI: 10.1039/C6RA28744A

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