Issue 82, 2017, Issue in Progress

Ag(i)/persulfate-catalyzed decarboxylative coupling of α-oxocarboxylates with organotrifluoroborates in water under room temperature

Abstract

The decarboxylative coupling reaction of α-oxocarboxylates and organotrifluoroborates was carried out smoothly in the presence of catalytic AgNO3 using K2S2O8 as oxidant to generate diarylketone products in high yields. The method is novel, simple, safe and efficient. Both aryl substituted potassium α-oxocarboxylates and organotrifluoroborates proceeded smoothly in water under room temperature. The utilization of α-oxocarboxylates as acylating agent presents some elements of interest.

Graphical abstract: Ag(i)/persulfate-catalyzed decarboxylative coupling of α-oxocarboxylates with organotrifluoroborates in water under room temperature

Supplementary files

Article information

Article type
Paper
Submitted
03 Oct 2017
Accepted
26 Oct 2017
First published
08 Nov 2017
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2017,7, 51928-51934

Ag(I)/persulfate-catalyzed decarboxylative coupling of α-oxocarboxylates with organotrifluoroborates in water under room temperature

S. Chang, J. F. Wang, L. L. Dong, D. Wang, B. Feng and Y. T. Shi, RSC Adv., 2017, 7, 51928 DOI: 10.1039/C7RA10924E

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