Issue 2, 2017
From the journal:

Chemical Science

Identification of monodentate oxazoline as a ligand for copper-promoted ortho-C–H hydroxylation and amination†

Ming Shang,a   Qian Shao,a   Shang-Zheng Sun,c   Yan-Qiao Chen,b   Hui Xu,a   Hui-Xiong Dai*a  and  Jin-Quan Yu*ab  

* Corresponding authors

a State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Shanghai 20032, China
E-mail: hxdai@sioc.ac.cn, yu200@scripps.edu

b Department of Chemistry, The Scripps Research Institute, 10550 N. Torrey Pines Road, La Jolla, California 92037, USA

c Department of Chemistry, Innovative Drug Research Center, Shanghai University, 99 Shangda Road, China

Abstract

The use of a weakly coordinating monodentate directing group for copper mediated ortho-hydroxylation and amination reactions allows for the identification of an external oxazoline ligand as a promoter.

Graphical abstract: Identification of monodentate oxazoline as a ligand for copper-promoted ortho-C–H hydroxylation and amination

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Article information

DOI
https://doi.org/10.1039/C6SC03383K
Article type
Edge Article
Submitted
30 Jul 2016
Accepted
21 Sep 2016
First published
26 Sep 2016
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2017,8, 1469-1473

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Identification of monodentate oxazoline as a ligand for copper-promoted ortho-C–H hydroxylation and amination

M. Shang, Q. Shao, S. Sun, Y. Chen, H. Xu, H. Dai and J. Yu, Chem. Sci., 2017, 8, 1469 DOI: 10.1039/C6SC03383K

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